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A powerful eye irritant in the smoke is

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Q. A powerful eye irritant in the smoke is
  1. Ozone
  2. Sulphur dioxide
  3. Carbon dioxide
  4. Peroxyacetyle nitrate
Answer: Peroxyacetyl nitrate

Peroxyacetyl nitrate is a peroxyacetyl nitrate. It is a secondary pollutant present in photochemical smog. It is thermally unstable and decomposes into peroxyethanoyl radicals and nitrogen dioxide gas. It is a lachrymatory substance.
Peroxyacetyl nitrate (PAN) is primarily responsible for the eye irritation so characteristic of this type of smog.

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